The Application of Bismuth-based Compounds in the Anode of Sodium-ion Batteries

Authors

  • Chengwei Shang

DOI:

https://doi.org/10.61173/xt43s044

Keywords:

Sodium-ion batteries, Bismuth vanadate, Bismuth molybdate, Bismuth ferrite, Specific capacity

Abstract

The sodium ion battery (SIB) system has outstanding advantages such as high experimental specific capacity, chemical principles similar to lithium-ion batteries, as well as abundant resources, making it an ideal next-generation energy storage system. At present, research on SIBs cathode materials is relatively abundant and has been applied to SIBs. However, for the anode material of SIBs, since the size of the sodium ion is relatively large, there are few materials available for the sodium ion storage, so it is still necessary to explore materials that combine high capacity with good cycling performance. Among numerous anode materials, bismuth compounds are regarded as one of the candidate materials for the anode of SIBs due to their excellent rate performance, high capacity, and relatively good safety performance. This article first introduces the current battery system and analyzes bismuth compound materials as SIBs anode materials. Subsequently, the author outlines the synthesis methods and electrochemical properties of different bismuth-based anodes. Finally, various bismuth-based materials are compared and the challenges they will face in the future are analyzed.

References

[1] Okika, M.C., Musonda, I. (2025). A Review: Charging infrastructure optimisation to support widespread adoption of electric vehicles. Energy Conversion and Management: X, 27, 101069.

[2] Hasan, M.M., et al. (2025). Advancing energy storage: The future trajectory of lithium-ion battery technologies. Journal of Energy Storage, 120, 116511.

[3] Nekahi, A., et al. (2025). Advanced Lithium-Ion Battery Process Manufacturing Equipment for Gigafactories: Past, Present, and Future Perspectives. iScience, 112691.

[4] Khalid, R., et al. (2025). Progress and obstacles in electrode materials for lithium-ion batteries: a journey towards enhanced energy storage efficiency. RSC Advances, 15(20), 15951-15998.

[5] Xu, H., et al. (2025). Comparative analysis of electrochemical properties and thermal behaviors of sodium ion and lithium ion batteries. International Journal of Electrochemical Science, 20(6), 101027.

[6] Yang, P., et al. (2025). Engineering ion transport in allsolid-state sodium-ion batteries: fundamentals, strategies, and perspectives. Progress in Materials Science, 154, 101503.

[7] Casino, S., et al. (2020). Protective coatings on silicon particles and their effect on energy density and specific energy in lithium ion battery cells: A model study. Journal of Energy Storage, 29, 101376.

[8] Man, X., et al. (2025). Prospect of bismuth and its compounds in sodium-ion batteries: A Review. Energy Storage Materials, 75, 104076.

[9] Cao, Y., et al. (2024). Bismuth nanoparticles embedded in carbon fibers as flexible and free-standing anodes for efficient sodium ion batteries. RSC Advances, 14(54), 39921-39926.

[10] Guo, S., et al. (2023). Micro-sized porous bulk bismuth caged by carbon for fast charging and ultralong cycling in sodium-ion batteries. Cell Reports Physical Science, 4(7), 101463.

[11] Chen, X., et al. (2024). Rational design of mangosteen-like bismuth nanospheres coated by N-doped carbon shell as superb composite anode for high-performance sodium-ion batteries. Journal of Energy Storage, 99, 113395.

[12] Xu, X., et al. (2020). Black BiVO4: Size tailored synthesis, rich oxygen vacancies, and sodium storage performance. Journal of Materials Chemistry A, 101039.

[13] Hu, A., et al. (2024). Hydrangea-like BiVO4–V2C endogenous heterostructure for superior Na+ storage. Journal of Power Sources, 592, 233921.

[14] Brennhagen, A., et al. (2022). Operando XRD studies on Bi2MoO6 as anode material for Na-ion batteries. Nanotechnology, 33, 185402.

[15] Ding, X., Liu, Yi. (2020). Hollow bismuth ferrite combined graphene as advanced anode material for sodium-ion batteries. Progress in Natural Science: Materials International, 30(2), 153-159.

Downloads

Published

2025-10-23