Physical and Chemical Adsorption of Hydrogen Storage Nanoporous Materials: Characteristics, Modifications and Applications
DOI:
https://doi.org/10.61173/b1p54043Keywords:
Material, adsorption, nanoparticles, hydrogen storage, organic frameworkAbstract
This article reviews the application and research progress of nanoporous materials in the field of hydrogen storage. Hydrogen energy is a type of clean energy source, hydrogen energy's efficient storage is the key to achieving hydrogen economy. The article first outlines the main kinds of adsorption of hydrogen storage technology, covering different methods such as physical adsorption technology, chemical adsorption technology and composite material adsorption technology. Subsequently, these technologies are further categorized and the materials that utilize these technologies are introduced, especially the performance characteristics and practical application of physical adsorption hydrogen storage materials (such as some carbon-based nanomaterials) and chemical porous materials (such as metal hydrides) were analyzed. It is especially pointed out in the article that the hydrogen storage capacity of nanomaterials can experience a significant improvement through microstructure optimization design and collaborative construction of composite materials. Finally, it is emphasized that reducing the working temperature and optimizing the pore size distribution are important ways to change the performance of hydrogen storage, and the future development prospects of the hydrogen economy are forecasted. Meanwhile, the practical application cases of physical adsorption materials, chemical adsorption materials and various hydrogen storage materials that have been optimized for treatment are listed in detail.
References
[1] Niemann M U, Srinivasan S S, Phani A R, et al. Nanomaterials for hydrogen storage applications: a review. Journal of Nanomaterials, 2008, 2008(1): 950967.
[2] Shaker L M, Al-Amiery A A, Al-Azzawi W K. Nanomaterials: paving the way for the hydrogen energy frontier. Discover Nano, 2024, 19(1): 3.
[3] Wang Y, Xue Y, Züttel A. Nanoscale engineering of solidstate materials for boosting hydrogen storage. Chemical Society Reviews, 2024, 53(2): 972-1003.
[4] Rimza T, Saha S, Dhand C, et al. Carbon‐based sorbents for hydrogen storage: challenges and sustainability at operating conditions for renewable energy. ChemSusChem, 2022, 15(11): e202200281.
[5] Singh R, Altaee A, Gautam S. Nanomaterials in the advancement of hydrogen energy storage. Heliyon, 2020, 6(7): e04487.
[6] Chen Z, Kirlikovali K O, Idrees K B, et al. Porous materials for hydrogen storage. Chem, 2022, 8(3): 693-716.
[7] Salaheldeen M, M. Abu-Dief A, El-Dabea T. Functionalization of nanomaterials for energy storage and hydrogen production applications. Materials, 2025, 18(4): 768.
[8] Latroche M, Surblé S, Serre C, et al. Hydrogen storage in the giant‐pore metal–organic frameworks MIL‐100 and MIL‐101. Angewandte Chemie, 2006, 118(48): 8407-8411.
[9] Rowsell J L C, Yaghi O M. Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal− organic frameworks. Journal of the American Chemical Society, 2006, 128(4): 1304-1315.
[10] Rowsell J L C, Millward A R, Park K S, et al. Hydrogen sorption in functionalized metal− organic frameworks. Journal of the American Chemical Society, 2004, 126(18): 5666-5667.
[11] Langmi H W, Ren J, North B, et al. Hydrogen storage in metal-organic frameworks: a review. Electrochimica Acta, 2014, 128: 368-392.
[12] Wong-Foy A G, Matzger A J, Yaghi O M. Exceptional H2 saturation uptake in microporous metal− organic frameworks. Journal of the American Chemical Society, 2006, 128(11): 3494- 3495.
[13] Liu S, Zhang Y, Zhu F, et al. Mg‐MOF‐74 derived defective framework for hydrogen storage at above‐ambient temperature assisted by Pt catalyst. Advanced Science, 2024, 11(18): 2401868.
[14] Palavesam N, Marin S, Hemmetzberger D, et al. Roll-toroll processing of film substrates for hybrid integrated flexible electronics. Flexible and Printed Electronics, 2018, 3(1): 14002.
[15] Aristizabal K, Katzensteiner A, Leoni M, et al. Evolution of the lattice defects and crystalline domain size in carbon nanotube metal matrix composites processed by severe plastic deformation. Materials Characterization, 2019, 154: 344-352.
[16] Wang Y, Zou K, Zhang D, et al. Cobalt–copper–boron nanoparticles as catalysts for the efficient hydrolysis of alkaline sodium borohydride solution. International Journal of Hydrogen Energy, 2020, 45(16): 9845-9853.
[17] Jimenez-Lopez L, Morales-Ospino R, Araujo L G, et al. Latest developments in the synthesis of metal-organic frameworks and their hybrids for hydrogen storage. Nanoscale, 2025, 17(11): 6390-6413.
[18] Cousins K, Zhang R. Highly porous organic polymers for hydrogen fuel storage. Polymers, 2019, 11(4): 690.
[19] Xing X, Liu Y, Zhang Z, et al. Hierarchical structure carbon-coated CoNi nanocatalysts derived from flower-like bimetal MOFs: enhancing the hydrogen storage performance of MgH2 under mild conditions. ACS Sustainable Chemistry & Engineering, 2023, 11(12): 4825-4837.
[20] Cheng H-M, Yang Q-H, Liu C. Hydrogen storage in carbon nanotubes. Carbon, 2001, 39(10): 1447-1454.
[21] Terry L R, Rols S, Tian M, et al. Manipulation of the crystalline phase diagram of hydrogen through nanoscale confinement effects in porous carbons. Nanoscale, 2022, 14(19): 7250-7261.
[22] Gogotsi Y, Portet C, Osswald S, et al. Importance of pore size in high-pressure hydrogen storage by porous carbons. International Journal of Hydrogen Energy, 2009, 34(15): 6314- 6319.
[23] Sethia G, Sayari A. Activated carbon with optimum pore size distribution for hydrogen storage. Carbon, 2016, 99: 289- 294.
[24] Xie J, Zhang H, Li S, et al. Defect‐rich MoS2 ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution. Advanced Materials, 2013, 25(40): 5807-5813.
[25] Yang S J, Choi J Y, Chae H K, et al. Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@ MOF-5 hybrid composite. Chemistry of Materials, 2009, 21(9): 1893-1897.
[26] Gao Y, Li Z, Wang P, et al. Experimentally validated design principles of heteroatom-doped-graphene-supported calcium single-atom materials for non-dissociative chemisorption solidstate hydrogen storage. Nature Communications, 2024, 15(1): 928.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 by the authors.

This work is licensed under a Creative Commons Attribution 4.0 International License.
