The advantages of Li-S car batteries and some solutions to the problems
DOI:
https://doi.org/10.61173/d5apdb49Keywords:
Li-S battery, “Shuttle Effect”, electric vehiclesAbstract
Rechargeable batteries has a significant impact in modern electronic devices, it powers various applications, from mobile phones or laptops that are portable devices to bigger machines including electric vehicles. Li-ion batteries, however, start to reach its limitation. It is urgent to find out new solutions, in many choices, lithium–sulphur batteries is a famous candidate due to the high ability of storing electricity in chemical energy within smaller volumes and lighter weight, the friendliness to the environment and the large number of raw materials. However, several challenges are obstacles of LSB practical deployment, including the insulating property of sulphur, the solving ability and migration of lithium polysulfides and the large changing in volume during cycling. This article mainly focuses on solving problems including overusing of electrolyte, “shuttle effect” and low conductivity, which strongly hold back the commercialisation process. In order to develop LSB and enable it to be a next-generation energy storage solution in recent future.
References
[1] Alex K. Koech, Gershom Mwandila, Francis Mulolani, Phenny Mwaanga, Lithium-ion battery fundamentals and exploration of cathode materials: A review, South African Journal of Chemical Engineering, 2024, 50, 321-339
[2] G. Benveniste, H. Rallo, L. Canals Casals, A. Merino, B. Amante, Comparison of the state of Lithium-Sulphur and lithium-ion batteries applied to electromobility, Journal of Environmental Management, 2018, 226, 1-12
[3] Yu, Jing & Pinto-Huguet, Ivan & Zhang, Chao Yue & Zhou, Yingtang & Xu, Yaolin & Vizintin, Alen & Velasco Vélez, Juan & Qi, Xueqiang & Pan, Xiaobo & Oney, Gozde & Olgo, Annabel & Märker, Katharina & Silva, Leonardo & Luo, Yufeng & Lu, Yan & Huang, Chen & Härk, Eneli & Fleming, Joe & Chenevier, Pascale & Arbiol, Jordi. Mechanistic Insights and Technical Challenges in Sulfur-Based Batteries: A Comprehensive In Situ / Operando Monitoring Toolbox. ACS Energy Letters. 2024, 9, 6178-6214
[4] Yang, X., Li, X., Adair, K., Zhang, H., & Sun, X. Structural design of lithium–sulfur batteries: from fundamental research to practical application. Electrochemical Energy Reviews, 2018, 1(3), 239-293.
[5] Mohammad Rejaul Kaiser, Zhaojun Han, Ji Liang, Shi-Xue Dou, Jiazhao Wang, Lithium sulfide-based cathode for lithiumion/sulfur battery: Recent progress and challenges, Energy Storage Materials, 2019, 19, 1-15
[6] Lee, Jin Hong & Kang, Jisoo & Kim, Seung-Wan & Halim, Willy & Frey, Margaret & Joo, Yong. Effective Suppression of the Polysulfide Shuttle Effect in Lithium–Sulfur Batteries by Implementing rGO–PEDOT:PSS-Coated Separators via Air- Controlled Electrospray. ACS Omega. 2018, 3, 16465-16471
[7] Xiao-Tian Gao, Xiao-Dong Zhu, Liang-Liang Gu, Chuang Wang, Ke-Ning Sun, Yang-Long Hou, Efficient polysulfides anchoring for Li-S batteries: Combined physical adsorption and chemical conversion in V2O5 hollow spheres wrapped in nitrogen-doped graphene network, Chemical Engineering Journal, 2019, 378, 122189
[8] Guoxin Zhang, Bingyao Zhou, Guanyi Wang, Emmanuel Kornyo, Kevin Mathew, Jie Xiong, Yuzi Liu, Qingliu Wu, Mediating Li2S/S deposition behavior via balancing conductivity of carbon host and carbon-binder domain for prolonged Li-S battery cyclability, Journal of Power Sources, 2025, 653, 237778
[9] Wei Seh, Z., Li, W., Cha, J. J., Zheng, G., Yang, Y., McDowell, M. T., ... & Cui, Y. Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium– sulphur batteries. Nature communications, 2013, 4(1), 1331.
[10] Xiaoxiao Han, Jiyu Cai, Xin Wang, Yongqiang Liu, Hua Zhou, Xiangbo Meng, Understanding effects of conductive additives in lithium-sulfur batteries, Materials Today Communications, 2021, 26, 101934
[11] Dona Susan Baji, Shruti Kannan, Pooja B. Madambikattil, Arun Thirumurugan, Manoj Kumar Sharma, Ranjith Krishna Pai, Ananthakumar Ramadoss, Shantikumar Nair, Dhamodaran Santhanagopalan, Overarching advancements in building practical Li-S batteries: A holistic review, Journal of Energy Storage, 2024, 100, Part A, 113412,
[12] Gupta, A., Bhargav, A., & Manthiram, A. Highly solvating electrolytes for lithium–sulfur batteries. Advanced energy materials, 2019, 9(6), 1803096
Downloads
Published
Issue
Section
License
Copyright (c) 2025 by the authors.

This work is licensed under a Creative Commons Attribution 4.0 International License.
