Redox Flow Batteries for Long-Duration Energy Storage: Technology Overview, Market Status, and Sustainable Development Perspectives
DOI:
https://doi.org/10.61173/9acnaq69Keywords:
Redox flow battery, Long-duration energy storage, Renewable energy integrationAbstract
With the acceleration of the global energy transition and ambitious decarbonization targets put forward by various countries, long-duration energy storage (LDES) technology, as a core technology for solving the problem of intermittency of renewable energy sources, realizing the temporal and spatial regulation of the power system as well as supporting the deep decarbonization, has received extensive attention from both the academia and the industry. LDES batteries play an important role in the integration of renewable energy sources, such as wind and solar, due to their advantages of independent configuration of power and energy, high cycling efficiency and long lifetime. In this paper, we systematically sort out the mainstream liquid flow battery technology types such as vanadium, ferrochromium and zinc-bromine, analyze their technical characteristics and performance bottlenecks, and evaluate the market scale and regional development pattern, with a focus on typical. In the future, it is necessary to strengthen material innovation, system optimization and policy support to promote the progress of liquid flow battery technology towards higher performance, lower cost and wider application, and help the green transition and sustainable development of the global energy system.
References
[1] McNamara, J.W., DeAngelis, V., Byrne, R.H. et al. Longduration energy storage in a decarbonized future: Policy gaps, needs, and opportunities. MRS Energy & Sustainability 9, 142– 170 (2022). https://doi.org/10.1557/s43581-022-00037-9
[2] Piergiorgio Alotto, Massimo Guarnieri, Federico Moro,Redox flow batteries for the storage of renewable energy: A review,Renewable and Sustainable Energy Reviews, Volume 29,2014,Pages 325-335,ISSN 1364-0321, https://doi. org/10.1016/j.rser.2013.08.001.
[3] M. Shoaib, P. Vallayil, N. Jaiswal, P. Iyapazham Vaigunda Suba, S. Sankararaman, K. Ramanujam, V. Thangadurai, Advances in Redox Flow Batteries – A Comprehensive Review on Inorganic and Organic Electrolytes and Engineering Perspectives. Adv. Energy Mater. 2024, 14, 2400721. https://doi. org/10.1002/aenm.202400721
[4] Mordor Intelligence Research & Advisory. (2024 , February). Flow Battery Market Size - Industry Report on Share, Growth Trends & Forecasts Analysis (2025 - 2030). Mordor Intelligence. Retrieved May 18, 2025, from https://www.mordorintelligence. com/industry-reports/flow-battery-market
[5] United Nations General Assembly. (2015). *Transforming our world: The 2030 Agenda for Sustainable Development* (A/ RES/70/1). United Nations. https://sdgs.un.org Dean&Francis ISSN 2959-6157
[6] Weber, A.Z., Mench, M.M., Meyers, J.P. et al. Redox flow batteries: a review. J Appl Electrochem 41, 1137–1164 (2011). https://doi.org/10.1007/s10800-011-0348-2
[7] Khan, Taha. (2024, January 25). Vanadium Redox Flow Batteries Advance Large-Scale Energy Storage. AZoM. Retrieved on May 18, 2025 from https://www.azom.com/article. aspx?ArticleID=23328.
[8] FANG Maolin. Research progress of iron-chromium flow batteries technology[J]. Energy Storage Science and Technology, 2022, 11(5): 1358-1367
[9] Zhao, M., Cheng, T., Li, T., Xie, C., Yin, Y., & Li, X. (2025). A long-life zinc-bromine single-flow battery utilizing trimethylsulfoxonium bromide as complexing agent. Small Methods, *9*(4), Article 2401434. https://doi.org/10.1002/ smtd.202401434
[10] Subhadarshini, A., & Nanda, B. (2025). Zeolitic imidazolium framework (ZIF-8) and their derivative-based material for antibacterial study: A comprehensive review. Discover Materials, *5*(1), Article 50. https://doi.org/10.1007/s43939-025-00229-3
[11] MarketsandMarkets. (2024). How battery market size, share and trends (Report Code SE 5914). MarketsandMarkets. Retrieved from https://www.marketsandmarkets.com
[12] International Energy Agency. (2025). The state of energy innovation. [PDF file]. Retrieved from https://www.iea.org/ reports/the-state-of-energy-innovation
[13] Xia, Y., Ouyang, M., Yufit, V., Tan, R., Regoutz, A., Wang, A., Mao, W., Chakrabarti, B., Kavei, A., Song, Q., Kucernak, A. R., & Brandon, N. P. (2022). A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture. Nature Communications, *13*, 2388. https:// doi.org/10.1038/s41467-022-30044-w
[14] Hou, S., Chen, L., Fan, X., Fan, X., Ji, X., Wang, B., Cui, C., Chen, J., Yang, C., Wang, W., Li, C., & Wang, C. (2022). High-energy and low-cost membrane-free chlorine flow battery. Nature Communications, *13*(1), Article 1281. https://doi. org/10.1038/s41467-022-28880-x
[15] U.S. Department of Energy. (2012). *Categorical exclusion determination form: (0674-1537) ITN Energy Systems - Demonstration of a 2.5 kW/10kWh Redox Flow Battery (RFB) through rationally designed high energy density electrolytes and Membrane-Electrode Assembly (MEA)*
[16] Nambafu, G. S., Hollas, A. M., Zhang, S., Rice, P. S., Boglaienko, D., Fulton, J. L., Li, M., Huang, Q., Zhu, Y., Reed, D. M., Sprinkle, V. L., & Li, G. (2024). Phosphonate-based iron complex for a cost-effective and long cycling aqueous iron redox flow battery. Nature Communications, *15*, Article 2566. https://doi.org/10.1038/s41467-024-45862-3
[17] U.S. Department of Energy. (2022). 2022 Grid Energy Storage Technology Cost and Performance Assessment. Pacific Northwest National Laboratory.
[18] Yuan, Z., Liu, X., Xu, W., Duan, Y., Zhang, H., & Li, X. (2018). Negatively charged nanoporous membrane for a dendrite-free alkaline zinc-based flow battery with long cycle life. Nature Communications, 9(1), 3731. https://doi. org/10.1038/s41467-018-06209-x
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