Overview of Graphene Applications and Research in Flame Retardant Polymers

Authors

  • Yufeng Fan

DOI:

https://doi.org/10.61173/be7bnf36

Keywords:

Graphene, Novel composite flame retardant, Flame retardant mechanism and Modification

Abstract

The domestic and international research status of graphene flame retardant technology in polymer composites in recent years is reviewed, the research mechanism of graphene flame retardant technology in polymer composites and the preparation method are summarized, and the application and research overview of graphene in flame retardant polymers are summarized and prospected.

References

This carbon layer effectively blocks heat transfer and oxy- on polymer materials [J]. Polymer Bulletin, 2023, 36 (10): 1263- gen diffusion while adsorbing flammable volatiles, thereby 1274. delaying the combustion process. Additionally, graphene [3] Ma Wenjing, Wang Hanwen, Xu Fei, An Shijie, Zhu Zhiguo, exhibits significant synergistic effects when blended with Wang Wenqing, Wang Rui. Synthesis of Graphene-Loaded various flame retardants: Synergistic effects with metal Phosphorus-Nitrogen Composite Flame Retardants and Their hydroxides (such as magnesium hydroxide, Zn-Al layered Application in Polylactic Acid Modification [J]. Polymer

double hydroxides): Synergistic effects with phospho- Materials Science and Engineering, 2025, 41(01): 43-52. rus-nitrogen-based flame retardants: The phosphorus com- [4] Chen Qi, Zhang Yingqiang, Yang Chenxi, Hu Yuting, Li ponent catalyses polymer carbonisation, the nitrogen com- Zhijie. Research Progress on Flame Retardant Technology for

ponent releases inert gases, while graphene reinforces the Polymer Materials [J]. Shanghai Plastics, 2021, 49(04): 1-8. physical barrier function of the carbon layer, collectively [5] Hu Hongliang, Xie Wenbin, Li Jinghui. Research Progress significantly improving char residue rate and enhancing on Graphene Synergistic Flame-Retardant Polymer Composites smoke suppression effects. Experimental studies have [J]. Chemical Engineering Technology and Development, 2023, confirmed the excellent performance of graphene-based 52(09): 26-30. composite flame-retardant systems in various polymer [6] Ma Yalin, Wang Biaobing, Hu Guosheng. Current Status matrices. For example, the epoxy resin composite material of Research on Flame Retardants and Their Flame-Retardant

prepared by Guan[20]et al. (containing 68 wt% Al₂O₃, 7 Mechanisms [J]. Materials Reports, 2006, (S1): 392-395. wt% modified graphene nanosheets, and 5 wt% magne- [7] Di Yiru. Study on the synergistic flame-retardant sium hydroxide) exhibited a high oxygen index (39%) and performance of functionalised carbon nanotubes/bimetallic passed the UL-94 V-0 rating (no dripping). Adding just 1.5 hydroxide composites [D]. Supervisor: Zhang Haijun. Civil wt% Zn-Al/LDH@RGO hybrid material to epoxy resin Aviation University of China, 2022. significantly enhances fire resistance, as evidenced by a [8] Yang Feihao. Preparation of Graphene-Based Hybrid significant reduction in back temperature to 154.3°C, an Flame Retardants and Their Application in Epoxy Resins [D]. increase in expansion rate to 12.13, and an improvement Supervisor: Yu Chuanbai. Guilin University of Technology, in char yield to 32.2%. However, graphene still faces 2022. several challenges in flame-retardant applications: Dis- [9] Li Kun. Design of Layered Structures of Bimetallic persibility and compatibility issues: Graphene has poor Hydroxides and Their Flame Retardant Properties [D]. compatibility with polymer matrices and tends to agglom- Supervisor: Zhang Haijun. China Civil Aviation University, erate, often requiring functionalisation modifications (such 2022. as grafting phosphorus-nitrogen groups or metal oxide [10] Dong Shaotang, Xiao Guoqing, Chen Chunlin, Chen coating) to improve its dispersibility. Need for synergistic Chunyan, Yang Zhengwei, Zhong Fei, Wang Mingtan, Zou efficiency optimisation: The flame-retardant efficiency Rui. Zn-Al layered double metal hydroxide anchored reduced of graphene alone is limited, and systematic optimisa- graphene oxide for enhancing the fire performance of composite Dean&Francis Yufeng Fan coatings [J]. Colloids and Surfaces A: Physicochemical and composites by combination with graphene nanoplatelets and

Engineering Aspects, 2022, 632 magnesium hydroxide[J]. Composites Part B, 2016, 98 [11] Stanislav Trubachev, Alexander Paletsky, Egor Sosnin, [21] Liu Xiaoya, Yang Fusheng. Research progress on flame- Oleg Tuzhikov, Boris Buravov, Andrey Shmakov, Anatoliy retardant polymer composites [J]. Materials Review, Chernov, Ilya Kulikov, Albert Sagitov, Yuan Hu, Xin Wang. [22] Li Di. Study on polyvinyl chloride modified with graphite- Flame-Retardant Glass Fiber-Reinforced Epoxy Resins based flame retardants [D]. Supervisor: Liu Xiaohui. Tianjin with Phosphorus-Containing Bio-Based Benzoxazines and University of Technology, 2023.

Graphene[J].Polymers,2024,16(16): [23] Chen Nan, Zhong Guilin, Zhang Guofeng. Application and [12] Ding Fang. Construction of a Phosphorus-Nitrogen Element Mechanism of Graphene in Polymer Flame-Retardant Materials

Composite Flame-Retardant System and Its Application to [J]. Applied Chemistry, 2018, 35(03): 307-316. Polyester Fabrics[D]. Supervisor: Ren Xuehong. Jiangnan [24] Yang Guanjian, Wu Hongjun. Application and Research

University, 2023. Progress of Graphene in Polymer Flame-Retardant Materials [J]. [13] Mao Henan, Wang Xiaogong. Application of In Situ Chemical Engineer, 2017, 31(12): 62-64+57. Polymerisation in Graphene/Polymer Nanocomposites (English) [25] Wang Junzhe, Liang Jizhao. Application of Graphene, a [J]. New Carbon Materials, 2020, 35(04): 336-343. New Carbon Material, in Polymer Flame Retardants [J]. Colloids [14] Ko Ko Min Kaung Htet, Yeap Swee Pin, Abu Bakar Ayu and Polymers, 2015, 33(04): 185-189. Haslija. On Shape-Induced Interfacial Interactions in Graphene/ [26] Tang Yingying, Wang Jingyi, Wu Tao, Xu Jinlou, Jia Polyaniline Composite Produced Through In Situ Polymerisation Hongbing. Research Progress on the Application of Graphene in Approach [J]. Journal of the Taiwan Institute of Chemical Polymer Flame Retardants [J]. Synthetic Rubber Industry, 2013,

Engineers, 2023, 144 36(06): 490-495. [15] Li Yufeng, Zhao Yang, Liu Lishuang, Feng Feng, Gao [27] Ji Wei, Wang Jian, Dong Qun, Zhang Xuejia. Application Xiaohui, He Xifeng. Research progress on the preparation of and Development Trends of Flame Retardants in Plastics [J].

polymer/graphene composites by emulsion polymerisation [J]. Chemical Industry and Engineering, 2008, (02): 177-182.

Chinese Plastics, 2023, 37 (04): 112-120 [28] Abhrajit Debroy, M. Joyce Nirmala, Mrudula Pulimi, Willie [16] Kang Wei, Liu Xijun, Wang Yuwei, Yan Jie. Preparation of J.G.M. Peijnenburg, Amitava Mukherjee. Assessing the role of polymethyl methacrylate/modified graphene nanocomposites via graphene family nanomaterials (GFNs: Graphene, GO, rGO) in

emulsion polymerisation [J]. Plastics, 2021, 50 (01): 46-53. modifying the toxicity potential and environmental risk of the [17] Taher Alizadeh, Khalil Atayi. Synthesis of hydrogen flame retardant tetrabromobisphenol-A (TBBPA) in the marine

phosphate anion-imprinted polymer via emulsion polymerisation microalgae Chlorella sp. [J]. Chemosphere, 2024, 361 and its use as the recognition element of graphene/graphite paste [29] Kumar Ranjan, Mishra Sujeet Kumar, Hasnain S M potentiometric electrode [J]. Materials Chemistry and Physics, Mozammil, Pandey Shatrudhan, Deifalla Ahmed Farouk, 2018, 209 Jayapalan Sudeepan. Study of thermal and mechanical behaviour [18] Jiang Weijiao, Sun Chuandong, Zhang Yue, Xie Zhihui, by analysing the reinforcement effect of graphene nanoplatelets Zhou Jin, Kang Jian, Cao Ya, Xiang Ming. Preparation of well- on a polyamide-66 composite system developed via melt-mixing

dispersed graphene oxide-silica nanohybrids/poly(lactic acid) technique [J]. Materials Research Express, 2023, 10(10):

composites by melt mixing [J]. Polymer Testing, 2023, 118 [30] Ningning Hong, Jing Zhan, Xin Wang, Anna A. Stec, [19] Attar Suhail, Chen Biqiong, Cicala Gianluca, Catalanotti T. Richard Hull, Hua Ge, Weiyi Xing, Lei Song, Yuan Hu. Giuseppe, Scalici Tommasso, Falzon Brian G.. On the Enhanced mechanical, thermal, and flame-retardant properties by mechanical properties of melt-blended nylon 6/ethylene-octene combining graphene nanosheets and metal hydroxide nanorods copolymer/graphene nanoplatelet nanocomposites[J]. Polymer, for acrylonitrile–butadiene–styrene copolymer composite[J]. 2022, (prepublish): Composites Part A, 2014,64 [20] Fang-Lan Guan, Chen-Xi Gui, Hao-Bin Zhang, Zhi- [31] Shi Ling, Duan Xue. Development of flame retardants and

Guo Jiang, Yue Jiang, Zhong-Zhen Yu. Enhanced thermal their application in plastics [J]. Plastics, 2002, (03): 11-15. conductivity and satisfactory flame retardancy of epoxy/alumina

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Published

2025-08-26